Xenon hexafluororhodate

Xenon hexafluororhodate
Identifiers
CAS Number
  • none
3D model (JSmol)
  • Interactive image
  • F[Xe+].F[Rh-1](F)(F)(F)(F)F
Properties
Chemical formula
XeRhF6
Molar mass 348.1855 g/mol
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Xenon hexafluororhodate (XeRhF6) is a deep-red noble gas compound first synthesised in 1963 by Neil Bartlett.[1][2][3] It is analogous to xenon hexafluoroplatinate.[1]

Synthesis

Xenon hexafluororhodate is produced by the direct combination of xenon and rhodium hexafluoride:[3]

Xe + RhF6 → XeRhF6

References

  1. ^ a b Bartlett, Neil (1963). "New Compounds of Noble Gases: The Fluorides of Xenon and Radon". American Scientist. 51 (1): 114–118. JSTOR 27838621.
  2. ^ "Rare Gas Studies Lead to XeF". Chemical & Engineering News. 41 (5): 36–39. 1963. doi:10.1021/cen-v041n005.p036.
  3. ^ a b Pauling, Linus (1970). General Chemistry (3rd ed.). San Francisco: Dover. p. 250.
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Xenon compounds
Xenon(0)
  • AuXe4(Sb2F11)2
  • XeH+
Xenon(I)
  • XeCl
  • XePtF6
  • XeRhF6
  • XeRuF6
  • XePuF6
Xenon(II)
  • XeF2
  • XeFPtF5
  • XeFPt2F11
  • Xe2F3PtF6
  • XeCl2
  • XeBr2
  • FXeONO2
  • Xe(NO3)2
Organoxenon(II) compounds
  • XeC6F5F
  • XeC6F5C2F3
  • XeC6F5CF3
  • Xe(C6F5)2
  • XeC6F5C6H2F3
  • XeC6F5CN
  • Xe(CF3)2
  • Xenon(IV)
    • XeO2
    • XeF4
    • XeOF2
    • N(CH3)4XeF5
    • XeCl4
    Organoxenon(IV) compounds
  • XeF2C6F5BF4
  • Xenon(VI)
    • XeO3
    • XeF6
    • XeOF4
    • H2XeO4
    • NaHXeO4
    • XeO2F2
    • (NO)2XeF8
    • CsXeF7
    • RbXeF7
    • Cs2XeF8
    • Rb2XeF8
    Xenon(VIII)
    • XeO4
    • H4XeO6
    • XeF8 (predicted)
    Category:Xenon compounds
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    Noble gas compounds
    Helium compounds
    • HeH+
    • LiHe
    • Na2He
    • He2
    • He3
    Neon compounds
    • None known
    Argon compounds
    Krypton compounds
    Xenon compounds
    Xe(0)
    • AuXe4(Sb2F11)2
    • XeH+
    Xe(I)
    Xe(II)
    • XeF2
    • XeFPtF5
    • XeFPt2F11
    • Xe2F3PtF6
    • XeCl2
    • FXeONO2
    • Xe(ONO2)2
    • Organoxenon(II) compounds
    Xe(IV)
    • XeO2
    • XeF4
    • XeOF2
    • N(CH3)4XeF5
    • XeCl4
    • Organoxenon(IV) compounds
    Xe(VI)
    • XeO3
    • XeF6
    • XeOF4
    • H2XeO4
    • (NO)2XeF8
    Xe(VIII)
    • XeO4
    • H4XeO6
    • XeF8
    Radon compounds
    Rn(II)
    • RnF2
    • RnFSb2F11
    Rn(VI)
    • RnO3
    • RnF
      6
    Oganesson compounds (predicted)
    Og(0)
    • Og2
    Og(I)
    • OgH+
    Og(II)
    • OgF2
    • OgCl2
    • OgO
    Og(IV)
    • OgF4
    • OgO2
    • OgTs4
    Og(VI)
    • OgF6
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    Rh(0)
    Organorhodium(0) compounds
    • Rh4(CO)12
    • Rh6(CO)16
    Rh(I)
    • RhCl(P(C6H5)3)3
    Organorhodium(I) compounds
    • ((C2H4)2RhCl)2
    • ((C8H12)RhCl)2
    • ((C8H14)2RhCl)2
    • ((CO)2RhCl)2
    • HRh(P(C6H5)3)4
    • HRh(CO)(P(C6H5)3)3
    Rh(II)
    • Rh2(CH3CO2)4
    Organorhodium(II) compunds
    • Rh(C5H5)2
    Rh(III)
    • RhBr3
    • Rh(C5H5N)4Cl3
    • RhCl3
    • Rh(ClO4)3
    • RhF3
    • Rh(OH)3
    • RhI3
    • Rh(NH3)5ClCl2
    • Rh(NO3)3
    • Rh2O3
    • Rh2S3
    • Rh2(SO4)3
    • YbRh2Si2
    Organorhodium(III) compunds
  • ((CH3)5C5RhCl2)2
  • Rh(O2C5H7)3
  • Rh(IV)
    • RhO2
    • RhF4
    Rh(V)
    • RhF5
    • XeRhF6
    Rh(VI)
    • RhF6
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