Dysprosium titanate

Dysprosium titanate
Names
IUPAC name
Dysprosium titanate
Identifiers
CAS Number
  • 68993-46-4
3D model (JSmol)
  • Interactive image
InChI
  • InChI=1S/2Dy.7O.2Ti/q2*+3;7*-2;2*+4
  • [Dy+3].[Dy+3].[Ti+4].[Ti+4].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
Properties
Chemical formula
Dy2O7Ti2
Molar mass 532.727 g·mol−1
Density 6.8 g/cm3[1]
Structure[1]
Crystal structure
Pyrochlore
Space group
Fd3m, cF88, No. 227
Lattice constant
a = 1.0136 nm
Formula units (Z)
8
Related compounds
Other cations
Holmium titanate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

Dysprosium titanate (Dy2Ti2O7) is an inorganic compound, a ceramic of the titanate family, with pyrochlore structure.

Dysprosium titanate, like holmium titanate and holmium stannate, is a spin ice material. In 2009, quasiparticles resembling magnetic monopoles were observed at low temperature and high magnetic field.[2][3]

Dysprosium titanate (Dy2TiO5) is used since 1995 as material for control rods of commercial nuclear reactor.[4]

References

  1. ^ a b Dolgikh V.A., Lavat E.A. (1991). "Preparation of new oxide nitrides with the pyrochlore structure". Russ. J. Inorg. Chem. 36: 1389–1392.
  2. ^ "Magnetic Monopoles Detected In A Real Magnet For The First Time". Science Daily. 2009-09-04. Retrieved 2009-09-04.
  3. ^ Morris, D. J. P.; Tennant, D. A.; Grigera, S. A.; Klemke, B.; Castelnovo, C.; Moessner, R.; Czternasty, C.; Meissner, M.; Rule, K. C.; Hoffmann, J.-U.; Kiefer, K.; Gerischer, S.; Slobinsky, D.; Perry, R. S. (2009-09-03). "Dirac Strings and Magnetic Monopoles in Spin Ice Dy2Ti2O7". Science. 326 (5951): 411–4. arXiv:1011.1174. Bibcode:2009Sci...326..411M. doi:10.1126/science.1178868. PMID 19729617. S2CID 206522398.
  4. ^ Risovany, V.D.; Varlashova, E.E.; Suslov, D.N. (2000). "Dysprosium titanate as an absorber material for control rods". Journal of Nuclear Materials. 281 (1): 84–89. Bibcode:2000JNuM..281...84R. doi:10.1016/S0022-3115(00)00129-X.
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Dy(II)
  • DyCl2
  • DyI2
Dy(III)
  • Dy2Sn2O7
  • Dy2Ti2O7
  • Dy(CH3COO)3
  • Dy(C5H7O2)3
  • DySb
  • DyAs
  • DyBi
  • DyBr3
  • DyCl3
  • DyF3
  • Dy(IO3)3
  • DyI3
  • Dy(OH)3
  • Dy(NO3)3
  • DyN
  • DyPO4
  • Dy2O3
  • DyP
  • Dy2Se3
  • Dy2Te3
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Titanium(II)
  • TiCl2
  • TiH2
  • TiBr2
  • TiI2
  • TiO
  • TiS
  • TiSi2
Organotitanium(II) compounds
[(C5H5)2Ti(CO)2]
Titanium(III)
  • TiAl
  • TiBr3
  • TiCl3
  • TiF3
  • TiI3
  • TiN
  • TiP
  • Ti2O3
  • Ti2S3
Organotitanium(III) compounds
[(C5H5)2TiCl]2
Titanium(IV)
  • TiB2
  • TiBr4
  • TiC
  • TiS(S2)
  • TiCl4
  • Ti(ClO4)4
  • TiF4
  • H2TiF6
  • TiH4
  • TiI4
  • TiOSO4
  • Ti(NMe2)4
  • Ti(NO3)4
  • TiO2
  • H4TiO4
  • Ti(C2H3O2)4
  • Ti4(OCH2CH3)16
  • Ti(OCH(CH3)2)4
  • Ti(OCH2CH2CH2CH3)4
  • KTiOPO4
  • NiO·Sb2O3·20TiO2
  • TiS2
  • TiSe2
  • TiSi2
  • Ti(C
    3
    H
    5
    O
    3
    )
    4
Titanate compounds
  • BaTiO3
  • Ba2TiO4
  • Bi4Ti3O12
  • CaTiO3
  • CaCu3Ti4O12
  • CaZrTi2O7
  • Cs2TiO3
  • Dy2Ti2O7
  • EuBaTiO4
  • FeTiO3
  • Ho2Ti2O7
  • Li2TiO3
  • MnTiO3
  • Na2Ti3O7
  • Na0.5Bi0.5TiO3
  • Na2TiF6
  • K2TiF6
  • Li2TiF6
  • Rb2TiF6
  • NiTiO3
  • PbTiO3
  • Pb(Zr,Ti)O3
  • SrTiO3
  • ZnTiO3
Organotitanium(IV) compounds
  • [(C5H5)2TiCl2]
  • [(C5H5)2Ti(CH3)2]
  • [(C5H5)2TiS5]
  • [(C5H5)2Ti(μ-Cl)(μ-CH2)Al(CH3)2]
  • [(η5-C5H4-CH2C6H4OCH3)2TiCl2]
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Titanate salts
H He
Li2TiO3
Li4Ti5O12
Be B C N O F Ne
Na2TiO3 Mg Al Si P S Cl Ar
K CaTiO3 Sc Ti V Cr MnTiO3 Fe Co NiTiO3 Cu ZnTiO3
Zn2TiO4
Zn2Ti3O8
Ga Ge As Se Br Kr
Rb SrTiO3 Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs2TiO3 BaTiO3
Ba2TiO4
* Lu Hf Ta W Re Os Ir Pt Au Hg Tl PbTiO3 Bi12TiO20
Bi4Ti3O12
Bi2Ti2O7
Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La Ce Pr Nd Pm Sm EuTiO3 Gd Tb Dy2Ti2O7 Ho2Ti2O7 Er Tm Yb
** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No


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