1,1'-Dihydroxydicyclohexyl peroxide

1,1′-Dihydroxydicyclohexyl peroxide
Names
IUPAC name
1-(1-hydroxycyclohexyl)peroxycyclohexan-1-ol
Other names
Bis(1-hydroxycyclohexyl) peroxide
Identifiers
CAS Number
  • 2407-94-5 checkY
3D model (JSmol)
  • Interactive image
EC Number
  • 219-306-2
PubChem CID
  • 75477
UNII
  • 7XR9J84XLH checkY
UN number 3106
CompTox Dashboard (EPA)
  • DTXSID6062389 Edit this at Wikidata
InChI
  • InChI=1S/C12H22O4/c13-11(7-3-1-4-8-11)15-16-12(14)9-5-2-6-10-12/h13-14H,1-10H2
    Key: ZPOUDMYDJJMHOO-UHFFFAOYSA-N
  • C1CCC(CC1)(O)OOC2(CCCCC2)O
Properties
Chemical formula
 C12H22O4
Molar mass 230.304 g·mol−1
Appearance white solid
Melting point 66–68 °C (151–154 °F; 339–341 K)
Hazards
GHS labelling:
Pictograms
 GHS01: ExplosiveGHS05: CorrosiveGHS07: Exclamation mark
Danger
Hazard statements
 H240, H302, H314
Precautionary statements
 P210, P220, P234, P260, P264, P270, P280, P301+P312, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P330, P363, P370+P378, P370+P380+P375, P403+P235, P405, P411, P420, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound

1,1′-Dihydroxydicyclohexyl peroxide is an organic compound with the formula (C6H10OH)2O2. It is one of the peroxides derived from the reaction of cyclohexanone and hydrogen peroxide. Upon treatment with acid and additional peroxide, it converts to the cyclic diperoxide, bis(cyclohexylidene peroxide), (C6H10)2(O2)2.[1][2]

1,1′-Dihydroxydicyclohexyl peroxide is a catalyst for radical-initiated vulcanization.

References

  1. ^ Story, Paul R.; Lee, Bunge; Bishop, Clyde E.; Denson, Donald D.; Busch, Peter (1970). "Macrocyclic Synthesis. II. Cyclohexanone Peroxides". The Journal of Organic Chemistry. 35 (9): 3059–3062. doi:10.1021/jo00834a042.
  2. ^ McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J. (1980). "Ketone-Derived Peroxides. Part 1. Synthetic Methods". Journal of Chemical Research, Synopses: 34.